New PDF release: Analysis of Kinetic Models of Chemical Reaction Systems:

By L. A. Tavadyan, G. A. Martoyan

ISBN-10: 1631178652

ISBN-13: 9781631178658

English model of: Analiz kineticheskikh modelei khimicheskikh reak'tsionnykh sistem.

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Extra resources for Analysis of Kinetic Models of Chemical Reaction Systems: Value Approach

Example text

7) the rate of each reverse reaction may be estimated from experimentally measured data on the rates of reaction paths. Hence, the role of (s, -s) steps is revealed. I. Temkin [18] offers a method to derive the kinetic equations. 6) the rate of multistep reaction, is expressed through the rate constants of individual steps and characteristics, and more often concentrations of the initial substances, determined in kinetic experiments. In the final kinetic model the dependency on the rate constants of steps specifies their kinetic participation in the total chemical process [17].

Here the value parameter of a step also plays a vital role. 6) for estimating the contribution of an individual step are discussed below, where the calculational methods for the value magnitudes are described. , m . 7) In summary it may be said that for the assessment of kinetic significance for an individual step by the value method it is necessaty to take into account at first the value quantities of individual steps Gj, hj, and then value quantities of the species participating in the step according to the equation.

Conceptually, via this procedure kinetic “presence” of an individual step in the reaction system is identified. g. the function fitting experimental data. Frequently the use of a normalized sensitivity coefficient, representting a dimensionless quantity NSijF (t ) = (k j Fi ) Fi  k j = lnFi  ln k j is more suitable. 10) 24 L. A. Tavadyan and G. A. Martoyan Now let us address the question of calculating the sensitivity parameters. 11) where n is the number of individual steps, m is the number of initial and intermediate species in a multistep chemical reaction.

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Analysis of Kinetic Models of Chemical Reaction Systems: Value Approach by L. A. Tavadyan, G. A. Martoyan

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