By Tobin J. Marks
content material: value of metal-ligand bond energies in organometallic chemistry: an summary / Tobin J. Marks --
Periodic tendencies in transition steel bonds to hydrogen, carbon, and nitrogen / Peter B. Armentrout --
Organometallic response energetics from product kinetic strength liberate distributions / Petra A.M. van Koppen, Michael T. Bowers, J.L. Beauchamp, and David V. Dearden --
equipment for choosing metal-ligand and metal-metal bond energies utilizing fourier remodel mass spectrometry / Ben S. Freiser --
Gas-phase thermochemistry of organometallic and coordination advanced ions / David E. Richardson, Charles S. Christ, Jr., Paul Sharpe, Matthew F. Ryan, and John R. Eyler --
Ionization energy-bond power relationships in organometallic chemistry / Dennis L. Lichtenberger and Ann S. Copenhaver --
Thermodynamics and kinetics of transition metal-alkyl homolytic bond dissociation methods / Jack Halpern --
Cage pair intermediates and activation parameters / T. Koenig, T.W. Scott, and James A. Franz --
Thermodynamic and kinetic reviews of binding nitrogen and hydrogen to complexes of chromium, molybdenum, and tungsten / Alberto A. Gonzalez, Kai Zhang, Shakti L. Mukerjee, Carl D. Hoff, G. Rattan ok. Khalsa, and Gregory J. Kubas --
Thermodynamic stories of the hydrogenation and reductive coupling of carbon monoxide via rhodium(II) porphyrins / Bradford B. Wayland, Virginia L. Coffin, Alan E. Sherry, and William R. Brennen --
steel and ancillary coordination results on organolanthanide-ligand bond enthalpies : implications for bonding and response styles / Steven P. Nolan, David Stern, David Hedden, and Tobin J. Marks --
Novel extensions of the electrostatic covalent method and calorimetric measurements to organometallic platforms / Russell S. Drago --
Metal-ligand bond dissociation energies in CpMn(CO)₂L and Cr(CO)₅(olefin) complexes / Jane okay. Klassen, Matthias Selke, Amy A. Sorensen, and Gilbert ok. Yang --
Metal-carbon and metal-hydrogen bond dissociation enthalpies from classical and nonclassical calorimetric stories / A.R. Dias, H.P. Diogo, D. Griller, M.E. Minas da Piedade, and J.A. Martinho Simões --
Adsorbate-induced restructuring of surfaces : floor thermodynamic puzzle / G.A. Somorjai --
Acid websites on chemically changed molybdenum surfaces / Peter C. Stair --
Absolute electronegativity, hardness, and bond energies / Ralph G. Pearson --
Gas-phase chemistry of first-row transition steel ions with nitrogen-containing compounds : theoretical and experimental investigations / A. Mavridis, ok. Kunze, J.F. Harrison, and J. Allison --
Periodic tendencies within the bond energies of transition steel complexes : density sensible thought / Tom Ziegler and Vincenzo Tschinke.
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Additional info for Bonding Energetics in Organometallic Compounds
This is a reasonable result since angular momentum increases the energy of the tight transition state more than it does the loose orbiting transition state. This is illustrated in Figure 12. Loss of the higher / portion of the (E J) distribution results in products with less kinetic energy than would have been expected if the full (E,J) distribution were operative. This example is presented to express a cautionary note in analyzing kinetic energy release distributions. If the dynamical constraints had not been considered in fitting phase space theory to the data in Figure 11, an erroneously low bond dissociation energy would have resulted.
H a l l e , L. ; Crowe, W. ; Armentrout, P. ; Beauchamp, J . L. Organometallics 1984, 3, 1694. ; Armentrout, P. B. J . Phvs. Chem. 1988, £2, 7060. ^Reference 6. "Reference 27. H e t t i c h , R. ; F r e i s e r , B. S. J . Am. Chem. Soc. 1986, 108, 5086. ^Reference 26. E l k i n d , J . ; Armentrout, P. B. unpublished work. ch002 r u v x y z aa bb cc dd ee ff jd u 24 BONDING ENERGETICS IN ORGANOMETALLIC COMPOUNDS Single Metal Ligand Bonds. Metal Hydride Ions. The periodic trends i n t r a n s i t i o n metal ligand bonds can be understood by considering the simplest species, MH .
The recent development and application of techniques for studying the mechanisms and energetics of organometallic reactions in the gas phase stems in part from the importance of transition metal sites as active centers which provide low energy pathways for the selective catalytic transformation of small molecules into useful products. Considerable interest in the subject of C-H bond activation at transition-metal centers has developed in the past several years, stimulated by the observation that even saturated hydrocarbons can react with little or no activation energy under appropriate conditions.
Bonding Energetics in Organometallic Compounds by Tobin J. Marks