By A. Felinger
ISBN-10: 0080525563
ISBN-13: 9780080525563
ISBN-10: 0444820663
ISBN-13: 9780444820662
An outline of the numerical info research and sign therapy thoughts utilized in chromatography and comparable separation concepts, with emphasis at the description of the symmetrical and asymmetrical chromatographic top form versions. comprises sections on information acquisition, noise, top detection, and data thought. includes a thorough evaluate of the records of height overlap. either theoretical and empirical versions are mentioned. Of use not just in chromatography, yet in learning spectroscopic and different analytical signs.
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Extra resources for Data Analysis and Signal Processing in Chromatography
Example text
Harris and B. Kartochvil, Chemical Separations and Measurements, W. B. Saunders, Philadelphia, PA, 1974, Chapter 10. (7) L. B. Rogers, in I. M. Kalthoff and P. J. , Treatise on Analytical Chemistry, Part I, Vol. 2, Wiley, New York, 1961, Chapter 22. [8) D. C. , W. H. Freeman, New York, 1987, Chapter 23. [9) H. H. Willard, L. L. , J. A. Dean, and F. A. , Wadsworth, Belmont, CA, 1988, Chapter 1. (10) J. A. Bernard and R. Chayen, Modern Methods of Chemical Analysis, McGraw-Hill, New York, 1965, Chapter 6.
For ideal gas mixtures, which may be used to approximate the mobile phase of gas chromatography, Eq. 21) where P; is the partial pressure of component i. In developing the subsequent equilibrium expression, Eq. 18, P; replaces c; for any gaseous phases involved. Further details on the thermodynamics of solution equilibrium can be found in books on thermodynamics and solutions (5-11). 4 EQUILIBRIUM IN EXTERNAL FIELDS External fields are applied widely in separation systems. The most common fields used are based on electrical and sedimentation (both centrifugal and gravitational) forces.
38) Equations of this form were first developed by Hildebrand and Scatchard (see ref. 14). , solute i and solvent (3 in Eq. , the 8 values) of the pure solutes and solvents. Remarkably, the equations provide some guidance on solvent selection applicable not only to the small nonpolar molecules intended by theory but also to species of moderate polarity and size [14). 34 show that the heat of mixing of solute and solvent approaches zero whenever the /j values of the two substances are close; such substances mix readily.
Data Analysis and Signal Processing in Chromatography by A. Felinger
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