By Israel Rubinstein
ISBN-10: 0824773993
ISBN-13: 9780824773991
Offer finished, authoritative experiences on contemporary advancements and functions of well-established ideas within the box of recent electro- and electroanalytical chemistry, outlined in its broadest experience.
Read or Download Electroanalytical Chemistry: A Series Of Advances: Volume 21 PDF
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Additional info for Electroanalytical Chemistry: A Series Of Advances: Volume 21
Sample text
Results of Single-Molecule Permeation Experiments Results of such single-molecule permeation experiments, using the MV 2ϩ / Ru(bpy) 32ϩ pair (Fig. s, are shown in Fig. 17. The slopes of these permeation curves define the fluxes of MV 2ϩ and Ru(bpy) 32ϩ across the membrane. A permeation selectivity coefficient (α i )† can be obtained by dividing the MV 2ϩ flux by the Ru(bpy) 32ϩ flux. * The flux was determined by continuously monitoring the UV absorbance of the permeate solution by flowing the permeate through a UV detector.
For these studies, it is essential to use an anion that does not chemisorb to gold because we do not want the excess charge to be determined by chemisorption. Because F Ϫ does not chemisorb to Au [94], KF was chosen as the electrolyte. A concentration cell was assembled in which a gold nanotubule membrane separated solutions that were 1 mM and 10 mM in KF. 5 V versus Ag/AgCl. The E m values were measured at each applied potential (Fig. 12). The dashed lines at the top and bottom of Fig. 12 are the E m values that would be achieved if the nanotubule membrane showed ideal cation and ideal anion permselectivity, respectively [Eq.
Toluene is preferentially transported in the R ϭ -C 16H 33 membranes. This can be illustrated by defining the alternative selectivity coefficient α C16/OH (Table 3). As was the case for α OH/C16 , the α C16/OH values increase with decreasing tubule diameter. d. 9 nm membranes. 2 for p-xylene, and 16 for naphthalene. We suggest the following interpretation for these various data: Note first that of all the flux values reported in Table 3, the toluene fluxes in the Rϭ -C 16H 33 membranes are, in general, the highest.
Electroanalytical Chemistry: A Series Of Advances: Volume 21 by Israel Rubinstein
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