By Serge Zhuiykov
ISBN-10: 1420047612
ISBN-13: 9781420047615
Tracking emissions is a primary quandary for lots of industries, specifically these equivalent to the auto the place regulations are tightening every year. Zirconia-based sensors are typical while specificity, accuracy, and reliability are of paramount main issue. This ebook is the 1st to provide an in depth research of the electrochemistry, improvement, modeling, optimization, and know-how in the back of smooth zirconia-based sensors in addition to tailoring those sensors to fulfill particular business wishes. the writer can pay specific consciousness to the standards that confirm excessive sensitivity, significantly reports the constraints of present applied sciences, and surveys the wishes and chances of destiny advancements.
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Additional info for Electrochemistry of Zirconia Gas Sensors
Example text
13. F. , High-temperature electrolysis of gases, Moscow, Science Publishing, 1988, 232. 14. , Beitrag zur Theoric des Aulaufvorgaugs. I, Zeitschrift fur Phys. , Abt. B B 21 (1933) 25–41. 15. Nakamura, A. , Defect structure, ionic conductivity and diffusion in yttria stabilized zirconia and related oxide electrolytes with fluorite structure, J. Electrochem Soc. 133 (1986) 1542–1548. 16. , Beitrag zur Theoric des Aulaufvorgaugs. II, Zeitschrift fur Phys. , Abt. B, B 32 (1936) 447–462. 17. , Conduction domains for solid electrolytes, J.
3 (2006) 401–411. ) field at the contact between a metal electrode and a solid electrolyte is much stronger and extends over a much smaller regime than in the case of a semiconductor junction. This is owing to the much higher concentration of charge carriers in metals and solid ion-conductive electrolytes compared to semiconductors. 1 surface (a); the roughness of the Pt electrode, made of Pt paste, deposited on this surface (b); and the three-dimensional image of the surface of the Pt electrode deposited on YSZ (c).
18). They are adsorption–desorption of electrochemically active gaseous components on gas-electrolyte (GE) and gas-metal (GM) interfaces, ionization reaction (with electron transfer) on the metal-electrolyte (ME) and gas-electrolyte interfaces, and mass-transfer processes on all boundaries of three phases (gas-metal, gas-electrolyte, and metal-electrolyte). Furthermore, mass transfer of electrons and holes on the surface electrolyte layer may also occur. It is evident that the quantity of the current in the stationary state is equal to the quantity of the nonmetal component adsorbing on the gas-metal and gas-electrolyte surfaces as a result of ionization of this component on the ME and GE surfaces.
Electrochemistry of Zirconia Gas Sensors by Serge Zhuiykov
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